Reológia

Measuring Die Swell Using a Capillary Rheometer

Die swell has been used as a qualitative measure of polymer melt elasticity for quality control purposes in plastics industry. Die swell also can be used for analysis of extrudate smoothness in an extrusion process.

Die swell has been used as a qualitative measure of polymer melt elasticity for quality control purposes in plastics industry. Die swell also can be used for analysis of extrudate smoothness in an extrusion process.

Die swell is expansion of extrudate after exiting the die. It happens as a result of the molecular orientation that is generated by the flow in the die (with the greatest extension occurring near the wall) and recoiling after exiting the die (contracting in the flow direction and expanding in directions perpendicular to the flow).  In other words, this phenomenon is produced by plastic materials memory. As the extrudate exits the die, it tries to return to its initial molecular coil shape.

 

 

Dynisco LCR capillary rheometer is able to measure the diameter of the extrudates using a CCD element detection and laser beam. This accessory element has the following specification:  light source of 800 nm laser, resolution of 2.75 µm, measuring range of 0.13-23 mm, response time of 1.4 ms, and accuracy of +/- 0.003 mm.

 

 

There are two ways of measuring the die swell while using the capillary rheometer. Running die swell can be measured while piston is moving during a viscosity measurement (Steady State test type) while relaxed die swell can be measured after piston is stopped between viscosity measurements (Position and Delay sec test type).  Running die sell can be used to predict the die swelling condition of extrusion process while relaxed die swell can be used to predict the part dimensions. Also, die swell can be used to analyze the extrudate smoothness (part finish) as the extrudate distortion (e.g. shark skin, melt fracture, etc.) can produce a cyclical or noisy die swell measurements.   

By knowing the diameter of the die, the die swell ratio percentage can be calculated using equation below:


 

Figure 1 shows the die swell ratio percentage versus shear rate for three different high density polyethylene samples.

 


Figure 1. Die swell ratio percentage versus shear rate for three PP samples.

 

As it was expected, the die swell ratio decreases with decreasing shear rate, as for lower shear rate, viscoelastic plastic materials forget their elastic memory and as a result die swell decreases.

Die swell can be troubleshooted by using a larger die diameter, longer die, tapering the die, decreasing the shear rate, or increasing the temperature.